Second-Layer Induced Island Morphologies in Thin-Film Growth of Fullerenes
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Author list: Korner M, Loske F, Einax M, Kuhnle A, Reichling M, Maass P
Publisher: AMER PHYSICAL SOC
Place: COLLEGE PK
Publication year: 2011
Journal acronym: PHYS REV LETT
Volume number: 107
Issue number: 1
Number of pages: 4
ISSN: 0031-9007
Languages: English-Great Britain (EN-GB)
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Abstract
Deposition of fullerenes on the CaF(2)(111) surface yields peculiar island morphologies with close similarities to previous findings for (100) surfaces of other ionic crystals. By means of noncontact atomic force microscopy we find a smooth transition from compact, triangular islands to branched hexagonal islands upon lowering the temperature. While triangular islands are two monolayers high, hexagonal islands have a base of one monolayer and exhibit a complicated structure with a second-layer outer rim and trenches oriented towards the interior. By developing a kinetic growth model we unravel the microscopic mechanisms of the structure formation.
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