Effect of attapulgite calcination on heavy metal adsorption from acid mine drainage

Journal article

Authors / Editors

Ntuli, Freeman

Research Areas

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Publication Details

Author list: Falayi T, Ntuli F

Publisher: Springer

Place: SEOUL

Publication year: 2015

Journal: Korean Journal of Chemical Engineering (0256-1115)

Journal acronym: KOREAN J CHEM ENG

Volume number: 32

Issue number: 4

Start page: 707

End page: 716

Number of pages: 10

ISSN: 0256-1115

eISSN: 1975-7220

Languages: English-Great Britain (EN-GB)

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Abstract

Attapulgite calcined at 973.15K was characterized and utilized as an adsorbent for the removal of heavy metals and neutralization of acid mine drainage (AMD) from a gold mine. Batch adsorption experiments were carried out using a thermostatic shaker. Activated attapulgite showed that it can neutralize AMD as it raised the pH from 2.6 to 7.3 after a residence time of 2 h. Metal ion removal after 2 h was 100% for Cu (II), 99.46% for Fe (II), 96.20% for Co (II), 86.92% for Ni (II) and 71.52% for Mn (II) using a 2.5% w/v activated attapulgite loading. The adsorption best fit the Langmuir isotherm; however, Cu (II), Co (II), and Fe (II) data fit the Freundlich isotherm as well. Calcination at 973.15 K resulted in the reduction of the equilibrium residence time from 4 to 2 h, solid loading reduction from 10 to 2.5% m/v and an increase in maximum adsorption capacity compared with unactivated attapulgite.

Keywords

Acid Mine Drainage, Adsorption, Attapulgite, Calcination, Heavy metal removal

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